Despite the growing visibility of middle-class women in diverse service sector jobs in Indian cities post 1991, scant research has been directed to study the linkage between their migration dynamics and post-liberalisation changes in the country. This article investigates the patterns and trends of urban migration of middle-class women through the period of pre- and post-liberalisation (1983 to 2007–08); and the socio-economic correlates of their contemporary migration using the data from the National Sample Surveys. Contrary to the dominant stereotypes around women’s “unproductive” migration, the middle-class women’s employment- and education-linked migration turns out to surpass their marriage and family associated movements. The multivariable regression analysis shows that labour migration of educated middle-class women becomes more probable for single, Scheduled Tribe women, aged 21–59 years, having a certificate/diploma, and work experience as a regular/salaried employee at the origin, and coming from rural areas of another state.